Modelling/Simulation of the synthesis of anti-corrosion coatings using the MOCVD process for low-carbon

Thesis topic details

General information

Organisation

The French Alternative Energies and Atomic Energy Commission (CEA) is a key player in research, development and innovation in four main areas :
• defence and security,
• nuclear energy (fission and fusion),
• technological research for industry,
• fundamental research in the physical sciences and life sciences.

Drawing on its widely acknowledged expertise, and thanks to its 16000 technicians, engineers, researchers and staff, the CEA actively participates in collaborative projects with a large number of academic and industrial partners.

The CEA is established in ten centers spread throughout France
  

Reference

SL-DES-25-0690  

Thesis topic details

Category

Engineering science

Thesis topics

Modelling/Simulation of the synthesis of anti-corrosion coatings using the MOCVD process for low-carbon energy production

Contract

Thèse

Job description

The durability of materials used in many areas of energy production is limited by their degradation in the operating environment, which is often oxidising and at high temperature. This is particularly true of High Temperature Electrolysers (HTE) for the production of ‘green’ hydrogen, or the fuel cladding used in nuclear reactors to produce electricity. Anti-corrosion coatings can/should be applied to improve the lifespan of these installations, thereby conserving resources. A process for synthesising coatings using a reactive vapour route with liquid organometallic precursors (DLI - MOCVD) appears to be a very promising process.
The aim of this thesis is to model and simulate the DLI-MOCVD coating synthesis process for the two applications proposed above. Simulation results (deposition rate, deposit composition, spatial homogeneity) will be compared with experimental results from large-scale ‘pilot’ reactors at the CEA in order to optimise the model's input parameters. On the basis of this CFD simulation/experiments dialogue, the optimum conditions for deposition on a scale 1 component will be proposed. A coupling between CFD simulations and Machine Learning will be developed to accelerate the change of scale and the optimisation of scale 1 deposits.

University / doctoral school

Ingénierie - Matériaux - Environnement - Energétique - Procédés - Production (IMEP2)
Université Grenoble Alpes

Thesis topic location

Site

Saclay

Requester

Person to be contacted by the applicant

ROUILLARD FABIEN fabien.rouillard@cea.fr
CEA
DES/DRMP//S2CM
Bâtiment 458
pièce 113
91191 Gif sur Yvette
0169081614

Tutor / Responsible thesis director

BOICHOT Raphaël raphael.boichot@simap.grenoble-inp.fr
CNRS
Laboratoire SIMaP
1130 Rue de la Piscine 38402 Saint Martin d’Hères
04 76 82 66 77

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