General information
Organisation
The French Alternative Energies and Atomic Energy Commission (CEA) is a key player in research, development and innovation in four main areas :
• defence and security,
• nuclear energy (fission and fusion),
• technological research for industry,
• fundamental research in the physical sciences and life sciences.
Drawing on its widely acknowledged expertise, and thanks to its 16000 technicians, engineers, researchers and staff, the CEA actively participates in collaborative projects with a large number of academic and industrial partners.
The CEA is established in ten centers spread throughout France
Reference
SL-DES-24-0831
Thesis topic details
Category
Technological challenges
Thesis topics
Develoment of lithium mediated ammonia electrolyzer
Contract
Thèse
Job description
Recent developments in electrochemical ammonia (NH3) synthesis using lithium (Li) metal deposition in THF-based electrolytes in the presence of protic species, reinvigorated the research interest in direct NH3 electrolyzes technology thanks to its surprisingly high performance in terms of synthesis rate and faradaic efficiency. However, the main drawback is poor energy efficiency due to minimum voltage requirements associated to Li metal deposition and H2 oxidation reactions on the opposite electrodes. In this project, we propose to study the nitridation reaction of Li-alloy forming metals that can enable the decrease in electolyzer voltage. This study will be performed using a 3-electrode electrochemical pressure cell and differential scanning calorimetry – thermogravimetric analysis under N2, H2 pressures. The goal here is to couple existing knowledge in chemical looping synthesis of ammonia with electrochemical synthesis. Porous (carbon or steel tissue) electrodes will be developed with nanoparticles of Li-alloy forming metals and their performance will be studied in an electrolyzer. The assumed 3-step reaction mechanism to form NH3 is as follows: Li deposition > nitridation > protonation. This mechanism is already a subject of discussion for pure Li metal which will be further complicated with the use of alloy forming metals. Therefore, we propose an in-depth study using x-ray photoemission spectroscopy. The ultimate objective of the project is to accelerate the direct NH3 electrolysis technology and address the Power-to-X needs of renewable electricity sources.
University / doctoral school
Ingénierie - Matériaux - Environnement - Energétique - Procédés - Production (IMEP2)
Université Grenoble Alpes
Thesis topic location
Site
Grenoble
Requester
Position start date
01/11/2024
Person to be contacted by the applicant
HAJIYEV Parviz Parviz.HAJIYEV@cea.fr
CEA
DRT/DTNM/STDC/LVME
04.38.78.69.47
Tutor / Responsible thesis director
BENAYAD Anass anass.benayad@cea.fr
CEA
DRT/DTNM//L2N
MINATEC Campus | 17 rue des martyrs | F-38054 Grenoble Cedex
04 38 78 17 19
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