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Synthetic methodologies towards functionalized azaheterocycles and application to energetic molecules


Thesis topic details

General information

Organisation

The French Alternative Energies and Atomic Energy Commission (CEA) is a key player in research, development and innovation in four main areas :
• defence and security,
• nuclear energy (fission and fusion),
• technological research for industry,
• fundamental research in the physical sciences and life sciences.

Drawing on its widely acknowledged expertise, and thanks to its 16000 technicians, engineers, researchers and staff, the CEA actively participates in collaborative projects with a large number of academic and industrial partners.

The CEA is established in ten centers spread throughout France
  

Reference

SL-DAM-26-0189  

Direction

DAM

Thesis topic details

Category

Condensed Matter Physics, chemistry, nanosciences

Thesis topics

Synthetic methodologies towards functionalized azaheterocycles and application to energetic molecules

Contract

Thèse

Job description

The objective of the PhD is to develop new synthesis and/or functionalization methods to obtain functionalized heterocyclic molecules. These molecules are based on 5- or 6-member azaheteroaromatic rings (diazines, triazines, triazoles, tetrazoles, etc.). The targeted structures make it possible to envisage high densities and enthalpies of formation, while maintaining low sensitivity (thermal, mechanical, etc.). They find applications in the energy field, notably propulsion, explosives and gas generators (airbags). In addition, these heterocyclic compounds as well as the intermediates are also structurally close to families of biologically active products and/or likely to exhibit fluorescence properties, as already shown in a previous PhD in the laboratory.

University / doctoral school

Energie - Matériaux - Sciences de la Terre et de l’Univers (EMSTU)
Orléans

Thesis topic location

Site

Le Ripault

Requester

Position start date

01/11/2026

Person to be contacted by the applicant

PASQUINET Eric eric.pasquinet@cea.fr
CEA
DAM/DXPL
CEA/Le Ripault
BP16 - 37260 MONTS
02 47 34 40 00

Tutor / Responsible thesis director

SUZENET FRANCK franck.suzenet@univ-orleans.fr
ICOA
UMR-CNRS 7311
Institut de Chimie Organique et Analytique, Université d’Orléans, UMR-CNRS 7311, LRC CEA M09, 45067 Orléans, Cedex 2
0238494580

En savoir plus



https://www.icoa.fr/fr/heterocycles-nucleosides-et-agents-dimagerie/chimie-heteroaromatique-conception-de-molecules-bioactives-et-de-sondes-pour-limagerie-optique/