Gold nanoparticles (AuNPs) possess unique electronic, photonic, and chemical properties of invaluable interest in a variety of medical and technological applications. They are typically produced by controlled chemical precipitation from a salt solution to achieve the precise size control critical for most applications. Continuous flow microreactors, which efficiently mix the salt solution and the reducing agent, are known to offer improved size control. However, even in these reactors, the smallest AuNPs can only be formed using powerful reducing agents that are harmful to human health or the environment. We propose to minimize their impact and to develop a more resource-efficient process by inserting an electrochemical cell into the reactor to form the reducing agent in-situ in the adjusted amount necessary to produce the desired AuNPs.
Your goal will be to test and adapt continuous-flow electrochemical cells for the synthesis of AuNPs, exploring various electrochemical reactions and cell designs. You will also explore the use of several capping agents of biological interest. A careful examination of AuNPs characteristics (size, interfacial and optical properties, etc.) will guide you in this research.