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Structural evolution under electron irradiation of lamellar hydroxydes and hydrates

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Thesis topic details

General information

Organisation

The French Alternative Energies and Atomic Energy Commission (CEA) is a key player in research, development and innovation in four main areas :
• defence and security,
• nuclear energy (fission and fusion),
• technological research for industry,
• fundamental research in the physical sciences and life sciences.

Drawing on its widely acknowledged expertise, and thanks to its 16000 technicians, engineers, researchers and staff, the CEA actively participates in collaborative projects with a large number of academic and industrial partners.

The CEA is established in ten centers spread throughout France
  

Reference

SL-DRF-24-0532  

Direction

DRF

Thesis topic details

Category

Condensed Matter Physics, chemistry, nanosciences

Thesis topics

Structural evolution under electron irradiation of lamellar hydroxydes and hydrates

Contract

Thèse

Job description

The societal context of the study is the optimization of cementitious matrices for nuclear waste conditioning. These cementitious matrices are composed of hydrated minerals, some of which are lamellar (portlandite Ca(OH)2, brucite Mg(OH)2, brushite CaHPO4.2H2O, gibbsite Al(OH)3...). Very few data exist in the literature on the structural damage of these hydrated lamellar minerals under electron irradiation. The aim of the proposed thesis is to experimentally investigate irradiation-induced structural modifications in various types of compounds, with a view to gaining a better understanding of the damage mechanisms of these compounds under irradiation, and to identify irradiation sensitivity criteria in order to ultimately optimize the chemical and mineralogical composition of the materials.

University / doctoral school

Ecole Doctorale de l’Institut Polytechnique de Paris (IP Paris)
Ecole Polytechnique

Thesis topic location

Site

Saclay

Requester

Position start date

01/10/2024

Person to be contacted by the applicant

De Noirfontaine Marie-Noelle marie-noelle.de-noirfontaine@polytechnique.edu
CNRS
DRF/IRAMIS/LSI
LSI,
Ecole polytechnique,
Route de Saclay,
91128 Palaiseau

Tutor / Responsible thesis director

De Noirfontaine Marie-Noelle marie-noelle.de-noirfontaine@polytechnique.edu
CNRS
DRF/IRAMIS/LSI
LSI,
Ecole polytechnique,
Route de Saclay,
91128 Palaiseau

En savoir plus

https://www.polytechnique.edu/annuaire/de-noirfontaine-marie-noelle
https://portail.polytechnique.edu/lsi/fr/recherche/defauts-desordre-et-structuration-de-la-matiere